Designing large reverse osmosis systems

Posted on 12th Nov 2020

A picture of pressure vessels in a reverse osmosis system
Pressure vessels in a reverse osmosis system.

By Jeff Tate

Reverse osmosis (RO) is currently used in various applications ranging from small under the sink drinking water systems to large municipal drinking water applications. The technology is widely used and accepted as it removes both dissolved ionic and organic impurities.
This article will focus on the application of reverse osmosis membranes and discuss factors that should be considered for large systems. The system design of large RO systems should be considered to improve performance and membrane life.

A diagram of how reverse osmosis works.
How reverse osmosis works.

Commercial system design

Small commercial systems utilize 2.5” and 4” diameter membranes. The membranes are typically housed in polyvinyl chloride (PVC) or stainless steel single membrane housings and installed in a vertical configuration. There may be some PVC or stainless steel piping, but hoses are typically used to connect the RO housings. This reduces the cost of the materials and assembly time. In commercial systems, the instrumentation is basic. Depending on the manufacturer, there are usually permeate and concentrate flow rotameters with a concentrate pressure gauge and a motor starter.

Usually, a preprogrammed microprocessor is used to start and stop the RO system, based on product level in the permeate storage tank. The microprocessors also have “pretreatment lockout” to prevent the RO system from running if a media filter is in backwash or softener is in regeneration. Pump low and high pressure protection is included for additional cost.

Pretreatment of commercial systems should include a multimedia filter, softener and activated carbon filter. The backwashable filter and softener vessels are fibreglass reinforced plastic (FRP) with a timer-based control valve. The RO system should include a “Big Blue” style plastic housing with pre-filter rated at five microns and a 304 stainless steel multistage pump. A stainless steel needle valve is used to control concentrate flow, and permeate flow varies. Depending on the manufacturer, some parts may be brass rather than stainless steel. This design is based on competitive price pressures and low cost of the RO membranes.

The commercial system design is controlled by the price. If the purchaser is educated to the benefits, concentrate recirculation, pre-filter inlet and outlet pressure gauges, pump throttling valve, soft motor starter or variable frequency drive, FRP vessels, so called “cold water” membranes and permeate pressure gauges can be included.
The commercial RO permeate flow rating is usually close to the maximum allowable of the RO membrane manufacturer, rather than based on the application and membrane flux. Recoveries are 20% to 50% without concentrate recirculation or as high as 75% with concentrate recirculation.

Since the feed water flow rate drops as permeate passes across the membrane, it becomes concentrated with high scaling and fouling containments the further across the membrane surface it flows. In order to minimize the fouling or scaling of the concentrate containments, a minimum flow is required to maintain high velocity and turbulence on the membrane surface. The concentrate recirculation option allows higher recoveries and less wastewater, by mixing feed water with rejected concentrate water.

Design of large reverse osmosis systems

With large systems, many RO membranes are used and the cost of the membranes is significant. Therefore, higher end “heavy industrial” and municipal reverse osmosis systems have a different design philosophy than their smaller commercial counterparts.

A reverse osmosis unit.
A small reverse osmosis unit.

The cost of the system is important, but greater weight is placed on the longer-term operation and maximum membrane life and performance. The 2.5” and 4” membranes cost between $100 to $350 and there are very few membranes on the system. So the membranes are regarded as disposable and replaced every year or two, even though the performance may have been degrading over time.

In industrial systems, there are multiple 8” membranes ranging from 18 to 180 per skid with six long vessels, and each membrane typically costs $600 to $800. Reliable performance in salt rejection and flow are critical for heavy industrial users. Often, the RO water is further polished by electrodeionization (EDI) to achieve ultrapure grade water without chemical regeneration.

Feed water sources

Feed water source is the first concern when designing a reverse osmosis system. The water source for brackish water membranes (BWRO) is typically surface or well water but could be industrial or municipal wastewater. Even if the source is municipally treated water, it is imperative to review where the municipality takes their water. This allows optimal system design as the characteristics of the water source will affect the RO membrane operation.

The water source indicates the potential for fouling and scaling. Fouling is the accumulation of solids on the membrane surface and/or feed spacer. Scaling is a chemical reaction where dissolved solids are precipitated out from the feed water on the concentrate side of the membrane. The most common forms of scaling are calcium carbonate, barium sulfate, calcium sulfate, strontium sulfate and calcium fluoride.
Surface water may be from lakes, rivers, reservoirs, etc. It is prone to fouling due to the seasonal fluctuations in suspended solids, biological contaminants and total organic carbon (TOC). Surface water tends to contain low total dissolved solids (TDS), heavy metals and hardness. Typically, surface water is chlorinated to kill bacteria, which results in high organic fouling potential. During rain, the suspended solids may increase.

The two most meaningful methods of measuring suspended solids are turbidity and Silt Density Index (SDI). Turbidity is most commonly measured in Nephelometric Turbidity Units (NTU) and is increased as the water’s ability to scatter light (transparency) decreases. SDI is a calculation of fouling potential according to test standard ASTM D-4189. It is calculated by flowing water through a 0.45 micron filter at 30 psi in a 500 ml jar, before and after a standard 15 minute run time through the filter. A percentage of plugging is calculated by comparing the time to fill a 500 ml jar with the RO feed water before the test (ti) to the time to fill a 500 ml jar with the RO feed water after the test(tf).

Formula for silt density index.
The formula for Silt Density Index (SDI). SDI is a calculation of fouling potential.

Turbidity should be less than 1.0 NTU for optimal performance. Acceptable SDI levels at the RO inlet are less than 5.0 (15 min test), but SDI should be less than 3.0 for optimal performance.

Well water usually contains very little suspended solids as the earth acts as a natural filter when water drains underground. Well water typically has higher dissolved solids and is frequently high in hardness and heavy metals, and possibly silica.

RO pretreatment is optimized based on the feed water characteristics and source. Suspended solids are removed by filtration. Media filtration is limited to filtering to 10 to 20 microns, while membrane filtration such as ultrafiltration can filter to 0.01 microns.

Scaling

Scaling potential is reduced by either ion exchange softening or chemical injection. Ion exchange (IX) softening is a reliable technology if regenerated properly. However, industrial ion exchange systems are more expensive than chemical injection. Industrial IX vessels require dual trains, ASME code carbon steel tanks, epoxy lined and painted and PLC controlled automatic valves.

Acid injection and antiscalant injection are two methods to reduce scaling on the membrane surface. Antiscalants are typically preferred over acid injection for several reasons. These include safety and product water carbon dioxide levels, which load polishing ion exchange or electrodeionization (EDI). If acid is used, hydrochloric acid is preferred over sulfuric acid as sulfuric acid can increase sulfate scaling potential.

Picture of a custom reverse osmosis system
A custom reverse osmosis system featuring pretreatment and electrodeionization polish.

Chemical injection simply requires a small storage tank filled with RO permeate and suitable antiscalants, level switches, manual isolation valves and a chemical metering pump. The appropriate antiscalant chemical is determined by the specific scaling ions, pH, and recovery. The chemical selection and dosage are supplied by the chemical supplier, but be sure to use a reliable manufacturer with experience in a full range of antiscalants based on the feed water and RO design.

Scaling potential is measured in Langelier Saturation Index (LSI) for brackish water. LSI is calculated by subtracting the calculated pH of saturation of calcium carbonate from the actual feed pH. LSI should be less than negative 0.2 if antiscalant injection is not used. Antiscalant injection permits LSI as high as 1.8 depending on the antiscalant used.

RO membranes cannot handle oxidizers, including free chlorine. If chlorine is in the feed water, it must be removed either by activated carbon filtration, or sodium metabisulfite injection. Activated carbon filters are more capital intensive than bisulfite injection. Bisulfite is also the preferred method as the carbon media is a known breeding ground for bacteria. The bisulfite can be manually controlled, but automatic control and proper set up will ensure chlorine is entirely scavenged without over injection of the bisulfite.

Over injection can cause sulfate reducing bacteria (SRB) growth. The instrumentation for control can be a reliable online titration free chlorine monitor, or oxidation reduction potential (ORP). The ORP set point will vary from site to site so an experienced technician should run titration tests to determine the optimal set point where ORP is set 30 to 50 mv lower than at which 0 ppm free chlorine is achieved. Manual free chlorine tests should be performed in routine maintenance.

Staging and selection of the RO membranes is based on the feed water and product water requirements. Over time, an increase in salt passage and decrease in flux is expected. The membranes have a three year warranty so a three year projection is typically used.
Salt passage increases as temperature increases so the warmest temperature is used to confirm permeate quality. The pressure required to pass the same permeate flow increases as temperature decreases. In commercial systems, a small pump capable of delivering the required flow at 77ºF, 500 or 1000 ppm is typically selected. When colder water enters the system, the user must settle for decreased flow.

A diagram of a membrane used in reverse osmosis systems.
A cut-away of a membrane used in reverse osmosis systems.

Industrial users require that the permeate flow be maintained at all times, so instead, the pump is sized based on the pressure and flow at the coldest temperature after a minimum of three years operation. The pump will be oversized at warmer temperatures, so a pump throttling valve or variable frequency drive is utilized to achieve desired flow.

The membrane flux also needs to be considered. Flux is the rate of permeate per membrane area, usually measured in gallons per square foot per day (gfd). Commercial systems usually rate the system around 20 gfd, which causes rapid decrease in product flow and quality. Industrial systems should be designed for no more than 16 gfd for well water, 12 gfd for surface water and 25 gfd for second pass (RO permeate feed water).

The manufacturer specifies a minimum concentrate flow and maximum feed flow for each model. Membrane selection, staging and system recovery are designed to meet the minimum requirements and not exceed maximum requirements (Table 1).
Salt passage design increase should be 3% to 17% per year, on average 10%.

Components in large reverse osmosis systems

The cartridge filter is also called an RO pre-filter. It protects the RO membranes by capturing suspended solids particles as the water passes through tubular elements (cartridges). The cartridge filter housing should be 316L stainless steel and the number and length of cartridge elements should be sized for 3.5 gpm per 10” length. The filters should have a nominal rating of no more than five microns.

The RO high pressure feed pump increases the feed water pressure to the required pressure for RO membrane operation. The pump should be specifically sized and selected for the temperature range and membranes at three-year operating conditions of the RO membranes. An industrial safety factor should be included in the pump sizing.

A picture of pressure vessels in a reverse osmosis system
Pressure vessels in a reverse osmosis system.

RO pressure vessels should be FRP and no longer than six membranes per vessel to allow optimal concentrate flow. They should be designed to meet the standards of the American Society of Mechanical Engineers (ASME) Boiler and Pressure Vessel Code, Section X. At an additional cost, vessels can be inspected during fabrication by an ASME authorized inspector and code stamped.

Membranes should be selected with appropriate salt rejection and staging to provide product water requirements for the temperature range and membranes at three-year operating conditions.

High pressure piping in the RO system should be 316L stainless steel for high corrosion resistance, fully fabricated and welded by qualified welders. All stainless steel fittings should be welded and threaded connections avoided wherever possible, to prevent leaks. Low-pressure piping should be Schedule 80 PVC. All piping should be hydrostatically tested with deionized water.

Automatic valves should be installed at the RO inlet, permeate, permeate divert, flush inlet and flush outlet.

Instrumentation should include the following:
• Flow sensors in the permeate and concentrate lines.
• Stainless steel liquid filled pressure gauges in the combined permeate outlet, concentrate outlet, and at each stage of the RO system to trend pressure drop across each stage.
• Pressure switches at the pump suction, pump outlet and across the cartridge filter.
• Conductivity probes should be installed at the system inlet and permeate.
• ORP or free chlorine and pH probes should be installed at system inlet, after chemical injection.
• An SDI test kid should be included with the system.

The control system is comprised of a programmable logic controller (PLC), with local 10” minimum colour touch screen human machine interface, and an optional Windows based operator station with remote monitoring capability.

In automatic mode the system operates automatically, based on a call for water and various other system parameters such as the quality of water, water flow rate, etc. The RO unit will start and stop based on the RO storage tank level.

The controller displays the inlet and permeate conductivity (TDS), water temperature, ORP, pH, flows along with the operating status of the pretreatment and RO and EDI. The controller monitors instrumentation and has an input to automatically start and stop, based on product water tank levels or other relay input. Upon shut down, it automatically flushes the RO membranes for several minutes using permeate water. In semi-automatic mode, the PLC controls and monitors all automatic functions of the train.

Manual adjustment and monitoring is necessary for manual system devices, such as manual valves and manual indicators. Bisulfite injection rate is controlled via bisulfite pump speed that in turn is controlled by a PID with ORP signal as the process variable. Set point for the ORP signal is determined in the field by titration.

A membrane clean-in-place (CIP) system is necessary for on-site chemical cleaning and sanitization. The CIP system is also used to prepare the RO membranes for long-term storage. Reverse osmosis CIP is a manual process of connecting the selected stage to the CIP system, mixing the proper chemicals in the CIP tank, and allowing the solution to recirculate through the selected stage.

Manual valves are provided at each stage inlet and outlet and to isolate the previous and following stages, in order to clean each stage individually. Hoses usually connect the CIP system to the appropriate RO or EDI skid, but hard piping provides for convenient cleaning.

The CIP system includes a conical bottom gallon high-density polyethylene tank designed to hold the necessary chemicals. The tank should have a low level switch for pump and heater protection.

Conclusion

In summary, reverse osmosis is a reliable and user friendly technology. The optimal reliability can be achieved by considering the feed water source and the user specific requirements such as permeate quality and maintenance capabilities. While some systems are provided with lowest capital cost, less maintenance, longer membrane life and reduced cleaning frequency can be achieve with a high quality system designed by knowledgeable and experienced engineers.

Jeff Tate is with Agape Water Solutions. This article originally appeared in ES&E’s September/October 2014 issue.

Above Selected Article is linked from below Website:

https://esemag.com/water/designing-large-reverse-osmosis-systems/

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